Toxicity of leather tanning wastewater effluents in sea urchin early development and in marine microalgae

This study was designed to investigate the composition and the toxicity of leather tanning wastewater and conditioned sludge collected at the leather tanning wastewater treatment plant (CODISO) located in Solofra, Avellino (Southern Italy). Samples were analyzed for their conventional parameters (COD, TSS, chromium and ammonia) and for metal content. Effluent samples included raw wastewater, and samples collected following coagulation/flocculation process and biological treatment. A set of toxicity endpoints were tested using sea urchin and marine microalgal bioassays by evaluating acute embryotoxicity, developmental defects, changes in sperm fertilization success and transmissible damage from sperm to the offspring, and changes in algal growth rate. Dose-related toxicity to sea urchin embryogenesis and sperm fertilization success was exerted by effluent or sludge samples according to the following rank: conditioned sludge > coagulated effluent > or = raw influent > effluent from biological treatment. Offspring quality was not affected by sperm exposure to any wastewater or to sludge samples. Algal growth was inhibited by raw or coagulated effluent to a similar extent and, again, the effluent from the biological treatment resulted in a decreased toxicity. The results suggest that coagulated effluent and conditioned sludge result in higher toxicity than raw influent in sea urchin embryos and sperm, whereas the biological wastewater treatment of coagulated effluent, in both sea urchins and algae, cause a substantial improvement of wastewater quality. Hence a final biological wastewater treatment should be operated to minimize any environmental damage from tannery wastewater.     

Differential sensitivities to hypoxia by two anoxia-tolerant marine molluscs: A biochemical analysis

The metabolic responses to a series of low oxygen tensions were compared for two species of Mediterranaean bivalves,Mytilus galloprovincialis andScapharca inaequivalvis. Whereas both species have well-developed and similar tolerances of anoxia, the metabolic responses ofS. inaequivalvis to low oxygen tensions indicate a substantially greater tolerance of hypoxia. Compared withM. galloprovincialis, the responses ofS. inaequivalvis included the ability to maintain a constant oxygen consumption down to a much lower pO₂ value (ca. 1.7 vs 3.4 ppm), and a lower critical pO₂ for the recruitment of fermentative pathways of ATP production (ca. 1 vs 3 ppm). Furthermore, a graded increase in the output of anaerobic products (succinate, alanine) occured at oxygen tensions below 3 ppm inM. galloprovincialis and reached a maximum at 1.6 ppm whereas inS. inaequivalvis the net accumulation of anaerobic products at the lowest oxygen tension tested (0.5 ppm) was still substantially less than the level of production output in complete anoxia. This suggests that fermentative pathways are maximally activated at all oxygen tensions below 1.6 ppm inM. galloprovincialis whereas rates of anaerobic pathways are still less than maximum at 0.5 ppm inS. inaequivalvis. These results indicate that in situations of declining oxygen tensions, such as occur due to eutrophication,M. galloprovincialis would not only begin to experience metabolic stress at higher oxygen tensions thanS. inaequivalvis but would experience greater stress at any given pO₂. Such differences in hypoxia tolerances may explain the success of the recently introducedS. inaequivalvis in out-competing the nativeM. galloprovincialis in the Adriatic Sea.This research was conducted at the Consorzio di Studi, Richerche ed Interventi sulle Risorse Marine, Viale Amerigo Vespucci 2, I-47042 Cesenatico (FO), Italy. Delta Institute for Hydrobiological Research, Yerseke, The Netherlands. Publication no. 554     

River flood risk and adaptation in Europe—assessment of the present status

Flood disasters have had a devastating effect worldwide over the past century, both in terms of human suffering and material losses. The study of these events and development of more effective adaptation and mitigation policies has become a priority, both in Europe and other parts of the globe. This paper detects and presents the spatial distribution of river flood risks in Europe. The methodology we developed involves an assessment of three key risk components: exposure, vulnerability and hazard. A topography-based flood hazard map of Europe, identifying low-lying areas adjacent to rivers, is presented and used to identify risk, together with land-use data and damage-stage relationship for different land uses. The study covers river flood risk for the entire European continent. This methodology can be used to determine the level of future risk, using the estimations on Hazard, Exposure and Vulnerability from specific climate and economic development models. Annual average flood damage is estimated for European regions, in absolute monetary terms and in % of regional Gross Domestic Product (GDP). The results highlight regions where the threat to the economy from river flood hazard is of major concern.     

Dynamic Procedure for Atypical Scenarios Identification (DyPASI): A new systematic HAZID tool

The availability of a hazard identification methodology based on early warnings is a crucial factor in the identification of emerging risks. In the present study, a specific method named Dynamic Procedure for Atypical Scenarios Identification (DyPASI) was conceived as a development of bow-tie identification techniques. The main aim of the methodology is to provide a comprehensive hazard identification of the industrial process analysed, joined to a process of continuous improvement of the results of the assessment. DyPASI is a method for the continuous systematization of information from early signals of risk related to past events. The technique provides a support to the identification and assessment of atypical potential accident scenarios related to the substances, the equipment and the site considered, capturing available early warnings or risk notions. DyPASI features as a tool to support emerging risk management process, having the potentiality to contribute to an integrated approach aimed at breaking “vicious circles”, helping to trigger a gradual process of identification and assimilation of previously unrecognised atypical scenarios.     

From landfill to water,land and life: The creation of the Centre for stone materials aimed at secondary processing

This paper focuses on the creation of a Centre for the recycling of stone materials. The Centre will be able to offer a range of activities amongst which is the improvement of the production chain of the Orosei Marble district in Sardinia, Italy. Several companies operate within the marble producing area, specializing in both quarrying and stone processing. They have formed a Consortium in order to rehabilitate an area of more than 17 ha. The restoration will be carried out through an environmentally sustainable procedure. The area was previously used as a landfill for waste deriving from marble quarrying and processing. At that time unshaped blocks of various sizes (which are unsuitable to block-cutter sawing), waste deriving from both block sawing and slab/strip cutting (such as broken slabs, strips, tiles) and microfine dust from filter presses of water treatment plants were representing an environmental problem. The local administration was struggling to find new areas which could be used for landfills, resulting in an additional cost for the landfill, ultimately affecting the variable production costs. The project involves the building of a venue to be used for temporary storage, treatment of wastes produced by both quarrying and primary processing, in order to make them suitable as secondary raw materials. The project also deals with the catch basin hydrology of the area involved in the project, the building of a multifunctional centre, the landscaping and other environmental features such as vehicle traffic and slopes greening.     

Detection of copper(II) and zinc(II) binding to humic acids from pig slurry and amended soils by fluorescence spectroscopy

The effect of the consecutive annual additions of pig slurry at rates of 0 (control), 90 and 150 m3 ha(-1) yr(-1) after a 7-year period on the Cu(II) and Zn(II) binding behavior of soil HAs was investigated in a field experiment. A fluorescence titration method and a single site model were used for determining metal ion complexing capacities and stability constants of metal ion complexes of HAs isolated from pig slurry and unamended and amended soils. With respect to control soil HA, pig-slurry HA featured much smaller Cu(II) and Zn(II) binding capacities and stability constants. Pig-slurry application to soil decreased Cu(II) and Zn(II) complexing capacities and binding affinities of soil HA. These effects increased with increasing the rate per year of PS application to soil, and are expected to have a large impact on bioavailability, mobilization, and transport of Cu(II) and Zn(II) ions in pig slurry-amended soils.     

COVID-19 pandemic: impacts on bees,beekeeping, and potential role of bee products as antiviral agents and immune enhancers

Environmental Science and Pollution Research - COVID-19 pandemic has passed to the front all the contradictions of the beekeeping sector: the valuable role of bee products as immune enhancers and...     

Multivariate tools to investigate the spatial contaminant distribution in a highly anthropized area (Gulf of Naples,Italy)

Environmental Science and Pollution Research - The Gulf of Naples located in a high anthropized coastal area is subjected to an infrastructural intervention for the installation of a submarine...